Effective and Economic Cleaning of High Ash Indian Coal for Cement and Sponge Iron Industries

Kalyan Sen, S.K.Mitra, N.S.Das, C.K.Das & T.Gouri Charan
Central Fuel Research Institute, Dhanbad - 828108

Introduction
India is endowed with vast reserves of coal1, nearly 241Bt, the non-coking counterpart of which is about 85%. About 31Mt of coking and 283Mt of non-coking coals were produced in India during the period 2000-20012. The greatest demand for coal is by electricity generating plants that burn mostly non-coking coals to produce electricity. The next important consumers are the metallurgical industries that consume primarily the coking coals. Some industries that find utilisation of non-coking coals include cement, smelting-reduction processes of steel making, sponge iron3, chemicals, paper, etc.

The cement industry is the third largest consumers of coal after power and metallurgy, requiring about 15 to 20 Mt of coal per annum. According to the report of CMIE, coal off-take by cement industry accounted to 15.6Mt during the period 1999-20002. After independence in 1947, the cement production in India took a turn from 1.5Mt per annum from 18 cement plants to about 135Mt of total installed capacity from 54 large capacity plants in private sector. India now becomes the second largest producer of cement in the world, crossing the production target of 100 Mt during fiscal 2001-20024 , and with coal as the primary source of fuel modern clean coal technologies like Sponge iron, Corex, Gasification, Liquefaction, etc.envisage better quality coal of specific characteristics. Non-coking coal (grade B/C) is the prime material required for these upcoming processes.

Coal plays a dual role in the sponge iron process by acting as reductant as well as a fuel for providing heat to maintain the requisite temperature inside the kiln at 950 -10500C. Consumption of non-coking coal in sponge iron industries alone is around 5Mt/annum. Apart from BSIL, the first commercial coal-based sponge iron plant, there are about 17 other large capacity sponge iron plants in India5. The small entrepreneurs in sponge iron manufacturing are mostly coal based. In Orissa, sponge iron industries are coming up in a big way5.

Coal quality requirement for cement and sponge iron industries 
The coal used for cement industry deserves satisfaction of some specific characteristics. The Indian Standard (IS-12770 -1989) for quality of coal is given in the table 1. For sponge iron industries, where the quality of coal varies widely depending on the variation in the technological propriety and process parameters, no stringent specification has been made till to date. As these industries are getting more and more emphasis compared to the high stake BF technology in India, it is high time that the consumers of this industry make conscientious efforts for preparing a national standard, so that the suppliers are encouraged to adhere to the desired quality of coal. This will lead to improvement in the production pattern. Table 2 represents an average quality specification as customized in sponge iron making. 
Cost of coals - present status for cement & sponge iron industries
Alike power and metallurgy, the cement and sponge iron industries are suffering from price hike in coal cost and railway freight, heterogeneity of multiple coal sources and ceaseless deterioration in quality of coal actually supplied to them. 


Though cement companies are one of the major consumers of coal, their traditional linkages with coal companies and inconsistent supplies lead to various 'technical problems'. To resolve these problems, the Ministry of Coal and the Government came forward to modify the coal-linkage agreements and accordingly, more than 90% of the cement producing units have signed, for the first time, individual coal-supply agreements with CIL6. However, posterior price hike by CIL of various grades of coal ranging from 4% to 12% would create a dent in their operating cost. An impact analysis7 on per bag cost of cement for the four major cement companies has been made based on the assumption that 100% of their coal requirement is met from CIL. The report reveals that a 5% hike leads to a 65 paisa rise in cost per bag of cement, whilst a 10% rise would amount to an increase of Rs1.30/bag. Among the larger cement producers, those who procure major share of coal requirement through imports, would not be adversely impacted.


Reduction in import duty from a figure of 25% to 20% on non-coking coal used for cement production as included in current budget would benefit only coastal-based plants in South and West India4. For some of these plants, non-coking coal accounts for 20-25% of total manufacturing cost. The biggest beneficiary would be cement plants in Tamil Nadu belonging to India Cements, Madras Cement and Dalmia Cements as most of the plants in the state depend on non-coking coal imported from Australia, South Africa and Indonesia.
The hikes in the freight rates on cement and coal have direct impact in increasing the cost per bag of cement. In the year 2000-01, the cement industry consumed nearly 10Mt of domestic coal. Railways also dispatched 39Mt of cement7. Over the years, the proportion of cement dispatched by railways has come down to 40% from nearly 70% in 1995.

Distance traversed

Coal

Cement

 

2000 km

1000km

  Freight cost (Rs/t)

1365.0

836.0

  % increase in 2001-2002

2.0

3.0

   Incremental increase in freight cost (Rs/t)

27.3

25.1

  Cost (Rsmn)

1392.3

861.1

  Total cement & coal dispatched through railways (Mt)

9.6

39.0

   Additional cost for the industry (Rs/Mt)

262.1

978.1

  Cumulative cost

1240.2

  Increase per bag (Rs)

0.7

Source: India Infoline estimates

According to Cement Manufacturers' Association (CMA)4, a 3.7% reduction in freight rates on cement & clinker and the proposition to offer station to station volume discounts may bring down the freight rates by at least Rs. 1 per bag of cement..
As already mentioned, the deteriorating trend in the coal quality is also a matter of grave concern to the industries. The main cause for deterioration in heat value is gradual depletion of quality coal from the upper horizons and also due to the ingress of extraneous mineral matter in the coal mined from open cast mines. Therefore, judicious beneficiation of available resources like inferior non-coking coal becomes a necessity, if not mandatory for large industries like, cement and smaller entrepreneurs like, sponge iron, etc. 
Technological barriers for beneficiation of high ash coal
More than 80 percent of Indian coals are of high ash and the quality of coal received by the consumers deteriorates continuously. The proposal by coal producers for setting up washeries under BOO format has not received sufficient response from the investors resulting to very little progress in setting up of coal beneficiation facilities till date. The existing conventional technologies based on which non-coking coal washeries are being installed in India are gradually failing to attract the end-users. After all, there can not be any single washing scheme that can be evaluated economically to beneficiate coals of varying washability characteristics to different quality the levels desired by the consumers. 


As a matter of fact, optimal beneficiation of non-coking coal needs a special approach from that of coking coal because of contrasted nature of constraints involved in their utilisation pattern, prevalent practice, existing infrastructure, availability of equipment etc. Indian coals are difficult to wash because of their close association and intermixing of the coal and inerts (both macerals and mineral matters) resulting from geological phenomena typical to Indian coals of Gondwana origin. Consequently, the separation criteria are quite complicated for these coals, except where the quality deterioration is mainly due to addition of overburden. Maximization of the recovery of clean coal at desired ash content being the major concern to the washeries, the perfection in predicting the anticipated yield of clean coal is a pre-requisite step in treating a coal in an existing washery or in designing a new plant8. 


The paper presents a case study of typical non-coking coals from Talcher coalfield, having ash content in the range of 40-41% for exploring the possible options for beneficiation routes. The characteristics of the coal and the size analysis is presented in the table 3. 

Crushing coal before or after washing - a predicament!
Natural breakage at the coal mineral interface in the course of mining and handling liberates a certain amount of obvious dirt. In case of superior coking coals, further liberation could be achieved through progressive levels of crushing leading to increase in yield of clean coal at desired ash level. In case of non-coking coals of Indian origin, our previous studies showed that size reduction below a certain limit does not facilitate significant liberation9. As cement and sponge iron industries may use coals of different size consists, it is imperative to resolve at the first hand, at what nominal top size the coal should be crushed prior to its further processing. Is it at 100/250mm as tolerated by the cement making processes or 25 mm as required by the sponge iron industry? Figure 1 showing the results of liberation study compares the theoretical recovery of cleans at different ash levels obtained from the coal crushed to 100 and 25mm respectively. The curves indicate no liberation up to an ash level of 24-25 percent. At higher ash levels, overall recovery is affected by progressive crushing due to increasing fine (<3mm) generation. For obvious reasons, crushing raw coal to finer size before washing leads to more energy requirement, products de-watering and water effluent clarification problems than crushing the washed coal to the size as per the requirement of the consumers. Also, as discussed later, practically achievable yield from coal crushed to lower size is observed to be sometimes lesser at the lower ash content. Hence, washing the coal, preferably at larger size i.e. at 100mm top size seems to be beneficial while considering the poor liberation characteristics of Indian non-coking coals.
Choice of washers
Once the top size of crushing is selected, the choice of washer predominantly depends on the quality requirement of the consumers and the washability characteristics of the feed coal. Cement or sponge iron making warrants deep beneficiation of coal to an ash range 24-27%. Obviously, practical yield of clean coal obtained from a coal of definite size consist in dynamic conditions differs from the theoretical yield. The magnitude of difference depends upon the efficiency of separation of the washing unit. 


Computer simulation study on the washability data of the coal crushed to different size ranges, namely 100-3mm and 25-3mm has been made considering normal Imperfection values of different washing units and the results are represented in figures 2 and 3. Although Jigs are used more frequently than heavy-medium vessels because of their large capacities, low cost, adaptability to wide size range of coal and simple technique, they have the limitation in operating efficiently below 1.60 sp. gravity. The practical yield curves in figures 2 & 3 exhibit that Jigs or water-only washer (like Haldex, hyro-cyclone separator, etc.) can not be suitable washers to clean coal for cement and sponge iron making. Even more efficient Batac jigs would fail to achieve desired cleaning at ash level less than 25%. 


On the other hand, cleaning non-coking coal at desired ash level for both cement and sponge iron industries may be achieved in Heavy medium separator. It is observed that the practical recovery of cleans at 25% ash level is 38%, when 100-3mm fraction is treated in Heavy media for cement industry. A possible circuit may be, screening the coal to 25/13mm and washing the coarser fraction in HM bath followed by washing the finer fraction (-25/13 +3mm) in HM Cyclone, both having almost same imperfection value (Im about 0.05). It is interesting to note that even if the coal is crushed to 25mm as is currently practiced in sponge iron industries and washed in heavy medium cyclone, the practical recovery of cleans at 25% ash level would be lesser (about 34%), along with the additional problems of higher energy consumption, products dewatering and slurry/effluent treatment. 

Economical Aspect of washing process
The existing policy of coal producers for settings up washeries under BOO format has not received sufficient response from the investors, primarily due to uncertainty in return. As a matter of fact, there has been little progress in setting of non-coking coal beneficiation strategy till to date. The existing conventional technologies based on which most of the coal washeries are being installed in India are gradually failing to attract the end-users. After all, there can not be any single washing scheme that may be evaluated economically to beneficiate Indian coals of varying washability characteristics to the distinct levels desired by the consumers. 
However, the issue of beneficiating coal is largely dependent on other financial viability (like annual capacity, ownership of mines and minimum mineable reserve). Moreover, it requires study through trial runs on existing pilot plants and data-based modelling to evaluate the incremental impact on the cost component of every sub-process concerning the reduced ash content of coal.


A key element in process selection is maximum recovery of the product from raw coal at lowest possible cost. Selection of suitable circuit must be backed up by computer simulated washability data for prediction of yield gain over other circuits. In spite of the fact that heavy medium washing plants cost more to build and operate, the cleaning efficiency is comparatively more with more yield of cleans. As it happened in the case study, HM circuit may yield sometimes 6-8% extra washed coal at particular ash level when compared to the water only based washing units like jig, water only cyclones or hydro- separators. Considering washing as the single cost component, the higher cost involved with HM Cyclone (approx. Rs. 135/t of raw coal feed) compared to that with Jig (Rs. 85/t), may be compensated by yield gain achieved with the former. Moreover, the consumption of higher electrical energy for running the dynamic water only plants is also to be considered. The techno-economic analysis of a Coal preparation plant needs case to case study. 

Conclusion
The economic as well environmental benefits of using beneficiated coal in cement and sponge iron industries have been established but the need of more and more washeries is yet to be met. Washability characteristics of the raw coal should be prime criteria in selecting the washing circuit. Considering the poor liberation characteristics, Indian non-coking coals should be washed, preferably, at larger size and after washing cleans should be crushed as per the requirement of consumers.
Heavy medium baths/cyclones are the most efficient separator for deep washing of high ash Indian coals having high near-gravity material at separation point and can be operated at wide range of gravity from 1.30 to 1.80 with minimum cleans misplacement. Hence requirements of low ash coal (around 25 percent) for Cement and Sponge Iron Industry can be met by Heavy medium separators. Indigenous washed coal may supplement the imported coal, if desired. 


CFRI has undertaken R & D studies in a broad spectrum on indigenous non-coking resources. Samples have been collected from most of the major sources /projects of different coalfields of the country. The study would help in identification of suitable coals and in projecting most economically viable washing circuit for cement and sponge iron industries. 

Reference
1. Annual Report, G.S.I, January 2003.
2. CMIE, Energy volume, 2002.
3. The TISCO Direct Reduction Process for the Manufacture of Sponge Iron', Amit Chatterjee & Ramesh Singh, Fuel Science & Technology, Vol. 6 No. 1, Jan 1987 P 3-11.
4. Cement News Digest -Volume VII , No. 48 , Feb 2003.
5. 'Fortunes for Sponge Grade Iron Ore Deposits in Orissa', M. Sengupta & S. C. Ghosal, Journal of Mines, Metals & Fuels, 1998.
6. 'Cement units to sort out coal supply problems', Industry & Economy -Cement, BUSINESS LINE, Aug. 30, 2002.
7. 'Cement Sector Update -February, 2001'. India Infoline Sector Reports, Dec. 2002.
8. 'Economic Washing of Indian Power Coal & Availability of Indigenous Technology', Kalyan Sen and N. S. Das, Proceedings volume, seminar on Challenges facing Indian Coal, Coal Consumers Association of India, Kolkata, 21 Feb., 2002. 
9. 'Quality reassessment and evaluation of utilisation potential for Indian coals of Gondwana formation', Kalyan Sen, N. S. Das, A. Choudhury, Nandita Choudhury, S. K. Mitra, D. K. Chakraborty, R. K. Dutta & A. Mitra, Proceedings of International Conference on Processing of Gondwana Coal- Challenges and Solutions, 21-22 February, Kolkata, J. Mines, Metals & Fuels, 2003.

 

Table : 1 Requirements for Coal for Cement  Industry

 

 

 IS 12770 :1989

 

 

 

 

 

 

 

 

Sl . No.

Characteristics

Requirement

 

 

 

 

 

 

 

I)

Total Moisture content,

Max.  8

 

 

 

(at 60 percent RH and

 

 

 

 

40 deg. C) percent by

 

 

 

 

mass

 

 

 

ii)

Volatile matter,

Min.24

 

 

 

(air dry basis) percent

 

 

 

 

by mass

 

 

 

iii)

Ash, percent by mass

 

 

 

 

 

 

 

 

 

a)dry Process

Max. 27

 

 

 

b)Wet process

Max.24

 

 

iv)

Sulphur,percent by

 

 

 

 

mass

Max.0.8

 

 

v)

Chloride,percent by

Max.0.01

 

 

 

mass

 

 

 

vi)

Size, mm

Max.250

 

 

 

Table : 2  Requirements for Coal for Sponge iron

 

 

industry

 

 

 

 

 

 

Sl . No.

Characteristics

Requirement

 

 

 

 

 

I)

Total Moisture content,

6

 

 

(at 60 percent RH and

 

 

 

40 deg. C) percent by

 

 

 

mass,Max.

 

 

ii)

Grade  & UVH kcal/kg

B/C,  4940-6200

 

iii)

Fixed Carbon

>42

 

iv)

V.M. (air dry)                          

>30

 

v)

Ash, percent by mass,

22 to 25

 

 

 

 

 

vi)

IDT

>1280 deg C

 

 

 

 

 

 

 

 

 

vii)

Reactivity

>1.7 cc of CO

 

 

 

per gm of 'C'

 

 

 

 

 

viii)

Size, mm

-25+3

 

 

 

 

 

 

Source - OSI

 

 

 

 

 

Table : 3  

Characterisation of Coal under study

 

 

 

 

 

 

 

 

Proximate Ananlysis

 

 

 

 

 

   (Air  dried)

      (dry basis)

 

 

 

Moist%

6.5

-

 

 

 

Ash%

37.8

40.4

 

 

 

V.M. %

25.9

27.7

 

 

 

F.C.%

29.8

31.9

 

 

 

 

 

 

 

 

 

IDT

>1400

 

 

 

 

degree C

 

 

 

 

 

Equilibrated

4.7

 

 

 

 

Moist.%

 

 

 

 

 

 

 

 

 

 

 

Size Analysis

 

 

 

 

 

 

 

 

 

 

ROM Coal Crushed to 100

 

ROM Coal Crushed to 25 mm

 

 

 

 

 

 

Size,mm

Wt.%

Ash% (dry)

Size,mm

Wt.%

Ash% (dry)

 

 

 

 

 

 

100-75

29.7

42.5

25-13

57.4

42.2

75-50

25.0

40.8

13-10

8.3

41.3

50-25

19.0

41.1

10-3

18.6

39.3

25-13

11.2

39.7

-3

15.7

38.8

13-6

6.0

37.8

 

100.0

41

6-3

2.8

37.3

 

 

 

3-0.5

3.7

34.9

 

 

 

-0.5

2.6

41.0

 

 

 

 

100.0

40.6

 

 

 

 

 

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